Below the turbopause at an altitude of about 100 km (not far from the mesopause), the Earth's atmosphere has a more-or-less uniform composition (apart from water vapor) as described above; this constitutes the homosphere.^[6] However, above about 100 km, the Earth's atmosphere begins to have a composition which varies with altitude. This is essentially because, in the absence of mixing, the density of a gas falls off exponentially with increasing altitude, but at a rate which depends on the molar mass. Thus higher mass constituents, such as oxygen and nitrogen, fall off more quickly than lighter constituents such as helium, molecular hydrogen, and atomic hydrogen. Thus there is a layer, called the heterosphere, in which the earth's atmosphere has varying composition. As the altitude increases, the atmosphere is dominated successively by helium, molecular hydrogen, and atomic hydrogen. The precise altitude of the heterosphere and the layers it contains varies significantly with temperature. After loss of the hydrogen, helium and other hydrogen-containing gases from early Earth due to the Sun's radiation, primitive Earth was devoid of an atmosphere. The first atmosphere was formed by outgassing of gases trapped in the interior of the early Earth, which still goes on today in volcanoes. ^[7]

Density and mass

Main article: Density of air

The density of air at sea level is about 1.2 kg/m³(1.2 g/L). Natural variations of the barometric pressure occur at any one altitude as a consequence of weather. This variation is relatively small for inhabited altitudes but much more pronounced in the outer atmosphere and space due to variable solar radiation.

The atmospheric density decreases as the altitude increases. This variation can be approximately modeled using the barometric formula. More sophisticated models are used by meteorologists and space agencies to predict weather and orbital decay of satellites.

The average mass of the atmosphere is about 5 quadrillion metric tons or 1/1,200,000 the mass of Earth. According to the National Center for Atmospheric Research, "The total mean mass of the atmosphere is 5.1480×10¹⁸ kg with an annual range due to water vapor of 1.2 or 1.5×10¹⁵ kg depending on whether surface pressure or water vapor data are used; somewhat smaller than the previous estimate. The mean mass of water vapor is estimated as 1.27×10¹⁶ kg and the dry air mass as 5.1352 ±0.0003×10¹⁸ kg."

Evolution on Earth

See also: History of Earth

The history of the Earth's atmosphere prior to one billion years ago is poorly understood and an active area of scientific research. The following discussion presents a plausible scenario.

The modern atmosphere is sometimes referred to as Earth's "third atmosphere", in order to distinguish the current chemical composition from two notably different previous compositions. The original atmosphere was primarily helium and hydrogen. Heat from the still-molten crust, and the sun, plus a probably enhanced solar wind, dissipated this atmosphere.

About 4.4 billion years ago, the surface had cooled enough to form a crust, still heavily populated with volcanoes which released steam, carbon dioxide, and ammonia. This led to the early "second atmosphere", which was primarily carbon dioxide and water vapor, with some nitrogen but virtually no oxygen. This second atmosphere had approximately 100 times as much gas as the current atmosphere, but as it cooled much of the carbon dioxide was dissolved in the seas and precipitated out as carbonates. The later "second atmosphere" contained largely nitrogen and carbon dioxide. However, simulations run at the University of Waterloo and University of Colorado in 2005 suggest that it may have had up to 40% hydrogen.^[8] It is generally believed that the greenhouse effect, caused by high levels of carbon dioxide and methane, kept the Earth from freezing.

One of the earliest types of bacteria was the cyanobacteria. Fossil evidence indicates that bacteria shaped like these existed approximately 3.3 billion years ago and were the first oxygen-producing evolving phototropic organisms. They were responsible for the initial conversion of the earth's atmosphere from an anoxic state to an oxic state (that is, from a state without oxygen to a state with oxygen) during the period 2.7 to 2.2 billion years ago. Being the first to carry out oxygenic photosynthesis, they were able to produce oxygen while sequestering carbon dioxide in organic molecules, playing a major role in oxygenating the atmosphere.

Photosynthesising plants would later evolve and continue releasing oxygen and sequestering carbon dioxide. Over time, excess carbon became locked in fossil fuels, sedimentary rocks (notably limestone), and animal shells. As oxygen was released, it reacted with ammonia to release nitrogen; in addition, bacteria would also convert ammonia into nitrogen. But most of the nitrogen currently present in the atmosphere results from sunlight-powered photolysis of ammonia released steadily over the aeons from volcanoes.

As more plants appeared, the levels of oxygen increased significantly, while carbon dioxide levels dropped. At first the oxygen combined with various elements (such as iron), but eventually oxygen accumulated in the atmosphere, resulting in mass extinctions and further evolution. With the appearance of an ozone layer (ozone is an allotrope of oxygen) lifeforms were better protected from ultraviolet radiation. This oxygen-nitrogen atmosphere is the "third atmosphere". 200 – 250 million years ago, up to 35% of the atmosphere was oxygen (as found in bubbles of ancient atmosphere were found in an amber).

This modern atmosphere has a composition which is enforced by oceanic blue-green algae as well as geological processes. O₂ does not remain naturally free in an atmosphere, but tends to be consumed (by inorganic chemical reactions, and by animals, bacteria, and even land plants at night), and CO₂ tends to be produced by respiration and decomposition and oxidation of organic matter. Oxygen would vanish within a few million years due to chemical reactions and CO₂ dissolves easily in water and would be gone in millennia if not replaced. Both are maintained by biological productivity and geological forces seemingly working hand-in-hand to maintain reasonably steady levels over millions of years (see Gaia theory).

Air pollution

Main article: Air pollution

Air pollution is a chemical, physical (e.g. particulate matter) or biological agent that modifies the natural characteristics of the atmosphere in an unwanted way. Stratospheric ozone depletion due to air pollution (chiefly from chlorofluorocarbons) has long been recognized as a threat to human health as well as to the earth's ecosystems.

Worldwide air pollution is responsible for large numbers of deaths and cases of respiratory disease. Enforced air quality standards, like the Clean Air Act in the United States, have reduced the presence of some pollutants. While major stationary sources are often identified with air pollution, the greatest source of emissions is actually mobile sources, principally the automobile. Gases such as carbon dioxide, methane, and fluorocarbons contribute to global warming, and these gases, or excess amounts of some emitted from fossil fuel burning, have recently been identified by the United States and many other countries (see Kyoto accord), as pollutants.^{[citation needed]}

See also

• Aerial perspective
• Air glow
• Airshed
• Atmosphere (for information on atmospheres in general)
• Atmospheric chemistry
• Atmospheric dispersion modeling
• Atmospheric electricity
• Atmospheric models
• Atmospheric Radiation Measurement (ARM) (in the US)
• Atmospheric stratification
• Aviation
• Biosphere
• Compressed air
• Global dimming
• Global warming
• Greenhouse effect
• Historical temperature record
• Hydrosphere
• Intergovernmental Panel on Climate Change (IPCC)
• Lithosphere
• Meteorology
• US Standard Atmosphere

References

External links

• NASA atmosphere models
• NASA's Earth Fact Sheet
• American Geophysical Union: Atmospheric Sciences
• Layers of the Atmosphere
• Answers to several questions of curious kids related to Air and Atmosphere
• The AMS Glossary of Meteorology
• Paul Crutzen Interview Free video of Paul Crutzen Nobel Laureate for his work on decomposition of ozone talking to Harry Kroto Nobel Laureate by the Vega Science Trust.
• Slides describing the Earth's modern atmosphere

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